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A mechanism of the α–β structural phase transition (SPT) in V 2 O 5 is proposed. The driving force of the SPT is suggested to be the U 5 shear strain transforming the orthorhombic unit cell of the α-phase into the monoclinic unit cell of the β-phase. According to the model, the SPT is characterized by a concerted displacement of V 2 O 5 chains and is of martensitic...
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