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Process of the bromate anion reduction in the presence of a very low bromine concentration from an acidic solution for the one-dimensional transport under steady-state conditions has been analyzed theoretically. Bromate being non-electroactive in the potential range under consideration, its transformation takes place via the redox cycle composed by the reversible couple, Br2/Br−, and the irreversible...
Theoretical analysis of the system with coupled electrochemical and chemical steps has been carried out where bulk solution contains non-electroactive halogen oxoanions, XOn−, with a very small addition of halogen molecules, X2. The latter are electroreduced rapidly at the electrode surface, generating halide anions, X−, which diffuse towards solution, wherein they comproportionate with the principal...
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