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The new frontier of asymmetric catalyses by Pd(II) complexes is reviewed. Asymmetric catalyses of carbon–carbon bond formation by Pd(II) complexes are divided into transition metal catalysis and Lewis acid catalysis. Transition metal catalyses are observed in anomalous six-membered ring formation, ene-type cyclization leading to five-membered rings, spiro cyclization, alkaloid and quinoline synthesis,...
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