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Boronsäureester sind wichtige Verbindungen in der organischen Synthese. A. Studer und Mitarbeiter beschreiben in ihrer Zuschrift auf S. 17074 die übergangsmetallfreie radikalische Borylierung von Alkyl‐ und Aryliodiden. DMF als Lewis‐basisches Lösungsmittel ermöglicht diese Umsetzung, und die Reaktionen laufen über eine B‐B‐Ein‐Elektronen‐Bindung ab. Die Einleitung der Radikalkettenreaktion erfolgt...
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