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An improved protocol has been developed for the synthesis of symmetrical biaryl sulfides via a dominothiolation reaction using CuI as catalyst in the presence of DMAP as ligand. The coupling reaction of aryl halides was carried out in the presence of 5mol% of CuI and 20mol% of DMAP using thiourea as sulfur transfer agent. High yields of corresponding product were obtained by carrying out the reaction...
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