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Vinyl- and alkynyltrifluoroborates are rapidly converted to vinyl and alkynyl iodides under mild conditions using sodium iodide in the presence of chloramine-T. The reaction is stereospecific and proceeds in excellent yield.
Aryl- and heteroaryltrifluoroborates are rapidly converted to aryl and heteroaryl iodides under mild conditions using sodium iodide in the presence of mild oxidizing agents.
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