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Multi‐branched multi‐anchoring metal‐free dyes as photosensitizers for dye‐sensitized solar cells (DSSCs) are reviewed. The article outlines design strategies, main synthetic routes and optical and photovoltaic properties of two families of multi‐branched sensitizers: (a) D–(π–A)n (D = donor, π = π‐spacer, A = acceptor/anchoring functionality) structures containing arylamine, carbazole, phenothiazine...
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