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Two‐dimensional (2D) organic polymers have recently received considerable interest, especially those whose architectures are held together via supramolecular engineering. However, current approaches toward supramolecular 2D structures usually suffer from mutual interference of noncovalent interactions and lack of intrinsic functions. Herein, we report well‐regulated 2D supramolecular polymers (2DSPs)...
While many metal oxalate salts are known, few are known to form zeolite‐type topologies. The construction of zeolite types, especially those with low framework density such as RHO, from linear ligands is generally perceived as less likely, because the 180° metal‐ligand‐metal geometry deviates too much from the established strategy of using ligands with bent coordination geometry (centered around 145°)...
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