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Hybrid molecules of π‐conjugated carbon rings and BN‐heterocyclic rings (h‐CBNs) fused with each other have been a rare class of compounds due to the limited availability of their synthetic methods. Here we report the synthesis of new h‐CBNs featuring a B4N4‐heteropentalene core and polycyclic aromatic hydrocarbon wings. Using 1,2‐azaborinine derivatives as a building block, we developed a rational...
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