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To further increase the energy and power densities of lithium‐ion batteries (LIBs), monoclinic Li3V2(PO4)3 attracts much attention. However, the intrinsic low electrical conductivity (2.4 × 10−7 S cm−1) and sluggish kinetics become major drawbacks that keep Li3V2(PO4)3 away from meeting its full potential in high rate performance. Recently, significant breakthroughs in electrochemical performance...
In article number 1800567, Xianhong Rui, Chengchao Li, Shaoming Huang, and co‐workers review recent new advances in design and fabrication of nanostructured Li3V2(PO4)3 cathode materials and their enhancement of electrochemical properties. Nanostructured Li3V2(PO4)3 cathodes demonstrate enhanced electrical conductivity, high electrode/electrolyte contact interfaces, favorable electron and Li+ transport...
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