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Die Bredt‐Regel für Brückenkopfalkene ist für physikalisch‐organische Chemiker von großem Interesse, wurde jedoch selten auf Naturstoffe angewendet. In der Zuschrift auf S. 10754 ff. zeigen C. M. Williams und E.H. Krenske, wie Berechnungen der Olefinspannungsenergie, eingeführt von Schleyer, die Stabilität komplexer Naturstoffe mit Brückenkopfalkenen vorhersagen. Dies hilft, die Plausibilität der...
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