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Silicotungstat‐Liganden umranden eine Ag4‐Raute in den Clusterverbindungen TBA8[Ag4(DMSO)2(γ‐H2SiW10O36)2] ⋅2 DMSO⋅2 H2O (Ag4), die durch Reaktion von TBA4H4[γ‐SiW10O36] mit AgOAc in organischem Medium erhalten wurden (DMSO=Dimethylsulfoxid, TBA=Tetra‐n‐butylammonium). Die Polyoxometallate Ag4 (siehe Bild) katalysieren selektiv die hydrolytische Oxidation diverser Silane zu den entsprechenden Silanolen...
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