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Uranförderung: Zu den aktuellen Höhepunkten der urankatalysierten CO‐Umsetzungen zählt außer der reduktiven Kupplung oder CO‐Homologisierung auch die CO‐Hydrierung zu Methanolat mithilfe des gemischten Uran(III)‐Sandwich‐Komplexes 1. Der Katalysezyklus umfasst die urankatalysierte Hydrierung von 13CO zum Methanolatkomplex 2 mit nachfolgender Bildung von Me3SiO13CH3 und dem Urantriflat 3, das schließlich...
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