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The synthesis, structures, and emission properties of vaulted trans‐bis(salicylaldiminato)platinum(II) complexes 1 with diethylamino functionalities are described and compared with the non‐substituted analogues. The amino substitution provides an improvement of the linker dependence both for the color change of the trans‐bis(salicylaldiminato)platinum(II) platform in the glass state and for the acid‐induced...
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