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A triad compound, bis(3-py)-substituted TTF (L2) (py=pyridine; TTF=tetrathiafulvalene) was synthesized and characterized. The absorption spectroscopy and electrochemical properties of L2, and its protonated products were studied. The results of electronic absorption spectroscopy and cyclic voltammetry confirm that the mono- and di-protonated species of L2 are successively generated with the protonation...
Two ethylenedioxytetrathiafulvalenes substituted with a pyridinyl (Py) group (EDO-TTF-A) [A=3-Py (1) and A=4-Py (2)] have been synthesized to clear the nature of the donor–acceptor interaction between the TTF unit and a pyridine group, and characterized by 1 H NMR, mass spectra, elemental analyses and X-ray analysis. Cyclic voltammetry measurements show two steps of one-electron reversible...
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