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Two isomers of Ru5(C)(CO)14(O2CC6H5)(μ-H): Ru5(C)(CO)14(η2-O2CC6H5)(μ-H), 2 and Ru5(C)(CO)14(μ-O2CC6H5)(μ-H), 3 were obtained from the reaction of Ru5(C)(CO)15 with benzoic acid (PhCO2H). Both compounds were characterized structurally by X-ray diffraction analysis. Compound 2 contains an opened pentaruthenium cluster with a chelating benzoate ligand on the ruthenium atom that was opened. Compound...
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