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Durchbruch für chirale SPOs: Die Kombination sekundärer Phosphanoxide (SPOs) mit Phosphanen ergibt hocheffektive chirale Liganden für übergangsmetallkatalysierte Hydrierungen. Gemischte zweizähnige Liganden wie JoSPOphos und TerSPOphos sind schnell zugänglich, und ihre Eigenschaften sind leicht variierbar. In der asymmetrischen Hydrierung funktionalisierter Alkene erzielten Rh‐Komplexe dieser Liganden...
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