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Uranyl hybrid compounds are complex materials due to variability in coordination geometry, flexibility in ligand chelation, and metal hydrolysis, which leads to difficulty in controlling the secondary building units. The presence of transition metals in uranyl hybrid materials adds to the complexity, but also leads to an increase in the dimensionality of the topology from infinite chains and 2-D sheets,...
To explore the role of the organic linker in promoting curvature in hybrid uranyl materials, thiodiglycolic acid was used to create four U(VI) compounds: (C 5 H 6 N) 2 [(UO 2 ) 2 (tdg) 3 ](H 2 O) (1), (C 5 H 6 N) 2 [(UO 2 ) 2 (tdg) 3 ] (2), (C 7 H 8 )(C 5 H 6 N) ...
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