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We report the preparation of organometallic side‐wall complexes of single‐walled carbon nanotubes (SWNTs) under conditions, which allow the study of both mono‐ and bis‐hexahapto SWNT coordination compounds [(η6‐SWNT)Cr(CO)3, (η6‐SWNT)Cr(η6‐C6H6), (η6‐SWNT)2Cr]. The results are interpreted in terms of exohedral and endohedral binding of chromium to the SWNT sidewalls and ligand competition reactions...
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