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In the BiMVO5 series, only three representatives were found to show photoluminescence (PL) at room temperature, namely the compounds with M = Mg, Ca and Cd. Their optical properties are complex, but understood on the basis of the calculated electronic structures. Indeed, two antagonist behaviors are distinguishable by the existence (Mg, Ca) or not (Cd) of a broad area (∼0.9 eV above the bottom of...
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