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The synthesis of high‐molar‐mass first‐ and second‐generation, aromatic sulfonamide‐based dendronized polymers PG1(CH3) and PG1(NO2) as well as PG2(CH3) and PG2(NO2) has been achieved. For PG3(CH3) at least oligomeric material could be obtained. The polymers exhibit glass transition temperatures in the range of 135–162 °C and are valuable components for a presently ongoing in depth analysis of the...
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