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An der Luft‐Wasser‐Grenzfläche zeigen Radikale mit atmosphärenchemischer Relevanz ein anderes Verhalten als in Lösung oder in der Gasphase. In der Zuschrift auf S. 5509 ff. stellen M. F. Ruiz‐López et al. Computersimulationen zu den Radikalen HO2. und O2.− vor. Die effektive Dissoziationskonstante für den Zerfall von HO2. in Ionen und das Redoxpotential von O2.− sind an der Grenzfläche kleiner als...
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