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Considering that the predictive UNIFAC model is highly valuable for the solvent selection, process design and optimization of separation tasks, a large extension of this model to ionic liquid (IL)–solute systems is presented by combining experimental and COSMO‐RS derived databases. The experimental infinite dilution activity coefficient (γ∞) data of different solutes in ILs are first collected exhaustively...
When evaluating ionic liquids (ILs) for extractive desulfurization (EDS) of fuel oils, the inevitable presence of water in the system may have a significant and in many cases strongly negative effect. However, few studies have considered this particular issue and a promoted water effect on EDS is scarcely reported. In this work, COSMO-RS was firstly employed to calculate the capacity and selectivity...
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