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The iridium‐catalyzed reaction of imidazoles with formates in the presence of hydrosilanes as coreactants led to the production of 2‐[(alkoxy)(siloxy)methyl]imidazoles. Dimethyl acetylenedicarboxylate was the additive of choice for the reaction in terms of reaction efficiency. No reaction was observed in the absence of the hydrosilanes. Whereas substituents at the 1‐ and 5‐positions on the imidazole...
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