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Metal‐mediated base pairs formed by the coordination of metal ions to natural or artificial bases impart unique chemical and physical properties to nucleic acids and have attracted considerable interest in the field of nanodevices. AgI ions were found to mediate DNA polymerase catalyzed primer extension through the formation of a C–AgI–T base pair, as well as the previously reported C–AgI–A base pair...
HgII‐ und AgI‐Ionen lösen in Abwesenheit eines Watson‐Crick‐passenden Nucleotids spezifisch die durch DNA‐Polymerase katalysierte Primerverlängerung über die Bildung des T‐HgII‐T‐ und des erst entdeckten C‐AgI‐T‐Basenpaars aus. In der Zuschrift auf S. 6742 ff. zeigen H. Urata et al., dass dank der strikten Basenerkennung dieser Metallionen der geregelte Einbau der beiden verschiedenen Metallionen...
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