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Apyrase is an important family of extracellular enzymes that catalyse the hydrolysis of high‐energy phosphate bonds (HEPBs) in ATP and ADP, thereby modulating many physiological processes and driving life activities. Herein, we report an unexpected discovery that cerium‐based metal–organic frameworks (Ce‐MOFs) of UiO‐66(Ce) have intrinsic apyrase‐like activity for ATP/ADP‐related physiological processes...
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