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The ternary phases AlT2B2 (T=Fe, Mn, Cr) and quaternary phases AlFe2–xMnxB2 have been synthesized by arc-melting and characterized by powder X-ray diffraction, magnetic measurements, Mössbauer spectroscopy, and electronic band structure calculations. All the compounds adopt the AlFe2B2-type structure, in which infinite zigzag chains of B atoms are connected by Fe atoms into [Fe2B2] slabs that alternate...
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