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Metallazide eignen sich unter anderem für die Synthese von Nitridophosphaten und binären Nitriden. Hier zeigen wir einen neuen präparativen Zugang zu Aziden auf: Verschiedene Hauptgruppen‐, Übergangs‐ und Seltenerdmetalle reagieren mit wasserfreiem Silberazid in flüssigem Ammoniak unter Bildung der entsprechenden Metallazide. So wurden Mn(N3)2, Sn(N3)2 und Eu(N3)2 sowie deren Amminkomplexe zum ersten...
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