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We report on the phase equilibria, the homogeneity range, the crystal and electronic structure of the Φ phase in the Al–Mg–Zn system. The homogeneity range is similar at 360 °C and 330 °C and has a wedge-like shape. Al and Zn vary about 13 at.% and Mg maximal 2.5 at.%. The crystal structure has been characterized by X-ray single crystal structure refinement at two compositions Al 23.2 Mg ...
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