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Two diastereopure ligands, N,N′-bis(4-pyridyl)idene(1R,2R)- diaminocyclohexane (L 1 ) and N,N′-bis(3-pyridyl)idene(1R,2R)-diaminocyclohexane (L 2 ), have been synthesized and characterized. The interaction of L 1 with Ag(I) ions and L 2 with Cd(II) ions has been investigated. The structure of {[Ag(L 1 ) 2 ](CF 3 SO 3 )·4H 2 O}...
The synthesis and X-ray structure of a dinuclear nickel(II) complex of the triply deprotonated pentadentate Schiff base, N,N′-(2-hydroxypropane-1,3-diyl)bis(acetylacetoneimine) (apacaH 3 ), are reported. The complex, which was obtained by reaction of apacaH 3 with nickel acetate in ethanol, has a binuclear structure of type [Ni 2 (apaca)(OAc)] in which each metal centre is...
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