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Four novel coordination polymers (CPs) assembled with [2,2′‐bifuran]‐5,5′‐dicarboxylic acid (H2L) and metal ions ZnII, CdII or CoII have been successfully synthesized. Their molecular structures have been determined to be Zn(L)(H2O)2 (1), [Zn(L)(DMF)]2 (2), [Cd(L)(EtOH)(DMF)2]2 (3) and Co(L)(H2O)4·(H2O)2 (4) by crystallographic analysis. It is found that (2) exhibits a two‐dimensional infinite framework,...
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