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Aqueous acrylic–polyurethane hybrid emulsions (PUA) were fabricated by semibatch emulsion copolymerization using a mixture of acrylic (AC) monomers in the presence of an isocyanate terminated polyurethane (PU). The effects of PU content on the morphology of the hybrid emulsions and film properties were here investigated in detail using FT‐IR, UV, TEM, and SEM. TEM images clearly showed that hybrid...
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