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Synthesis of an interesting Ni(II) 1D-chain, [Ni 3 (ashz) 2 (DMF) 2 (H 2 O) 2 ] n ·4DMF (1·4DMF), derived from N-acetylsalicylhydrazide (H 3 ashz) has been reported. The unprecedented bridging coordination mode involving the phenoate oxygen of ashz 3− leads to the formation of a polynuclear 1D-chain without any additional spacer ligand...
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