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The titanium tetrazole coordination complex [TiCl 4 .(PhCN 4 H) 2 ] has been prepared by treatment of TiCl 4 with two equivalents of 5-phenyltetrazole in dichloromethane and spectroscopically and crystallographically characterised. The solid-state structure of this compound consists of six-coordinate titanium centres with cis ligated tetrazoles. The individual [TiCl...
The combination of 5-phenyl-1-H-tetrazole (tet) with AlR 3 in stoichiometries of 1-3 leads to the compounds [(tet)AlR 2 ] n R = Me (1), Et (2), i Bu (3), [(tet) 2 AlMe] n (4), and [(tet) 3 Al] n (5). The addition of pyridine to 1 leads to a soluble compound with the formulation, [(tet)AlMe 2 -pyridine] n (6). Likewise...
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