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Iron‐based metal‐organic frameworks (Fe‐MOFs) have attracted extensive interest from researchers due to their tunability, favorable properties, and chemical versatility. Compared with conventional porous materials, Fe‐MOFs exhibit better performance in a wide variety of applications. Herein, the structures of Fe‐MOFs are summarized to explore potential structures based on isoreticular chemistry, as...
Nonplanar porphyrins with out‐of‐plane distortions play crucial roles in many biological functions and chemical applications. The artificial construction of nonplanar porphyrins usually involves organic synthesis and modification, which is a highly comprehensive approach. However, incorporating porphyrins into guest‐stimulated flexible systems allows to manipulate the porphyrin distortion through...
The rational structural design of the electrode materials is significant to enhance the electrochemical performance for potassium ion storage, benefiting from the shortened ion diffusion distance, increased conductivity, and pseudo‐capacitance promotion. Herein, hydrated vanadium oxide (HVO) nanosheets with enriched oxygen defects are well confined into hollow mesoporous carbon spheres (HMCS), producing...