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π‐Radikalkationenkomplexe von Oxoeisen(IV)‐porphyrin (siehe Bild) dienen als Modelle für die Oxidation von Cl− zu einem aktiven Chlorierungsreagens, das verschiedenste organische Verbindungen chloriert. Hinweise sprechen dafür, dass Cl− über Cl. zu Cl2 oxidiert wird. Der Mechanismus umfasst entweder einen direkten Elektronentransfer oder die Bildung eines Eisen(III)‐hypochlorits mit anschließender...
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