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The reactions of Co(II) sources with N-salicylidene-o-aminophenol (H 2 saph), N-salicylidene-o-amino-4-methylphenol (H 2 saph-4Me) and N-salicylidene-o-amino-4-chlorophenol (H 2 saph-4Cl) were studied in MeOH. The new solid complexes (Bu4nN)[Co III (saph) 2 ] (1), (Et 3 NH)[Co III (saph-4Me) 2 ]⋅MeOH⋅MeCO 2 H (2⋅MeOH⋅MeCO ...
A systematic investigation of the reactions between metal ions and dipeptides containing the α-aminoisobutyric residue (Aib) was initiated. The solid complexes [Cu(H -1 L)] n (1, 2) and (LH 2 ) n [CuCl 3 ] n (3) were isolated and characterized by single-crystal X-ray crystallography, solid-state IR spectra and UV-Vis spectroscopy in solution (H...
A systematic investigation of the CuBr 2 /Mebta (Mebta=1-methylbenzotriazole) reaction system is described. Particular emphasis has been placed on determining the influence of the Mebta:Cu II ratio and the nature of solvent on the identity of the reaction products. These combined variations have led to the preparation of the following complexes; [CuBr 2 (Mebta)] n...
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