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The use of sterically hindered terphenyl-based carboxylate, − O 2 CAr 4F-Ph , in manganese (II) chemistry has yielded a new cubane-type Mn 4 cluster, in which four Mn(II) sites have slightly distorted octahedral geometries with a distinctive O 6 donor atom sets. Based on the total energy calculations for magnetic states of the cluster using the LDA+U method,...
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