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The explorative lanthanide coordination chemistry of 4′,5′-bis-(propylthio)tetrathiafulvenyl[i]dipyrido[3,2-a:2′,3′-c]phenazine (TTF-dppz) is described. Thereby, four new Ln(III) complexes, [Ln(NO 3 ) 3 (TTF-dppz) 2 ] with Ln(III)=Nd (1), Eu (2), Gd (3), Tb (4), have been prepared and characterized. An X-ray crystallographic study of [Gd(NO 3 ) 3 (TTF-dppz)...
Novel functionalized bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) derivatives 4 and 5 have been synthesized in good yields from cyano precursor via a cross-coupling reaction. Their redox potentials have been studied by cyclic voltammetry in a dichloromethane solution; this indicated that they are slightly weaker electron donors than BEDT-TTF. Compound 4 has been studied by X-ray crystallography;...
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