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The sequential reaction of a multisite coordinating compartmental ligand [2‐(2‐hydroxy‐3‐(hydroxymethyl)‐5‐methylbenzylideneamino)‐2‐methylpropane‐1,3‐diol] (LH4) with appropriate lanthanide salts followed by the addition of [Mg(NO3)2]⋅6 H2O or [Zn(NO3)2]⋅6 H2O in a 4:1:2 stoichiometric ratio in the presence of triethylamine affords a series of isostructural heterometallic trinuclear complexes containing...
Ten years ago, our research group synthesized for the first time the 2-pyrimidinecarboxylate anionic ligand by hydrothermal routes. In these years, a lot of researches have used this ligand to construct MOFs with interesting properties. We have designed MOFs by using 2-pyrimidinecarbonitrile as precursor and the possibilities are infinities. We show the great variety of structures that can be synthesized...
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