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Asymmetric Synthesis. In their Research Article (e202315872), Maria Besora, Montserrat Diéguez et al. report fast and highly selective Ir‐catalysts for the asymmetric hydrogenation of tetrasubstituted acyclic enones.
Die relative Reaktivität der C‐H‐Bindungen von Alkanen als Nucleophile gegenüber mehreren Silber‐, Kupfer‐ und Rhodium‐Carben‐Komplexen als starke Elektrophile wurde untersucht. In ihrer Zuschrift auf S. 14044 ff. zeigen P. J. Pérez et al., dass die C‐H‐Bindung von Methan das schwächste Nucleophil ergibt und sich daher auf der Treppe ganz oben befindet. Die anderen Bindungen folgen nicht dem allgemein...
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