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The open framework compound of [Gd 2 (BDA) 3 (DMF) 2 (H 2 O) 4 ]·2DMF (1), prepared by heating GdCl 3 with 2,2′-bipyridyl-4,4′-dicarboxylatic acid (BDA) in mixed solvent, is constructed from BDA linking up polymeric [GdO 5 (DMF)(H 2 O) 2 ] n tethers. The 1D channels are filled with coordinated and uncoordinated DMF molecules...
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