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In this review we focus both on major developments in new mass spectrometric techniques and on novel chemical applications of existing mass spectrometric techniques that have been reported since 1990. Emphasis is given to the application of these techniques to the study of bimolecular ion/molecule reactions, radiative association, and dissociative recombination of positive ions. Particular attention...
The occurrence or absence of proton transfer from derivatized fullerene trications C60H3+, to the parent neutral XH, is employed to obtain upper or lower limits to the apparent gas-phase acidity GAapp as well as to the estimated absolute gas-phase acidity. A comparison with the reactivity of analogous dicationic adducts indicates that C60XH3+ is generally more acidic than C60XH2+: for example, the...
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