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Seven new dioxidomolybdenum(VI) complexes [MoO2L1(X)].X (1) and [MoO2L2–7(X)] (2–7) [Where X=EtOH in case of 1 and 5 and X=DMSO in case of 2–4 and 6, 7] of aroylazines containing a bulky 3-hydroxy-2-naphthoic substituent, were isolated and structurally characterized. The aroylazine ligands H2L1–7 were derived from the condensation of 3-hydroxy-2-naphthoic acid hydrazide with several substituted aromatic...
Six Ru(II) complexes with formula [Ru(terpy)(L)]X (L=tridentate N,N,S− donor thiosemicarbazone ligands, X=PF6−) have been synthesized and characterized by using standard analytical and spectroscopic techniques. The X-ray crystal structures of the complexes [Ru(terpy)(L2)]PF6(2) and [Ru(terpy)(L3)]PF6(3) have been determined. It was found that during complexation the hydroxyimino functionality of the...
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