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Reactions of [(p-cymene)RuCl2]2 (1a) with dpmp ((Ph2PCH2)2PPh) in the absence or presence of KPF6 afforded the ionic complexes [{(p-cymene)RuCl2}(dpmp-P1,P3;P2){RuCl(p-cymene)}](X) (2a1: X=Cl; 2a2: X=PF6). A (p-cymene)RuCl moiety constructs a 6-membered ring coordinated by two terminal P atoms of the dpmp ligand and another one binds to a central P atom of the ligand. Reactions of [(C6Me6)RuCl2]2...
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