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A series of Fe(II) and Co(II) complexes with two chiral terpy ligands (L2, L3, L4 and L5) and a related pyridine-diimine (L6) have been prepared and structurally characterized. In all cases except one, the metals are five coordinated with an approximately trigonal-bipyramidal coordination sphere. The two lateral N-donor atoms occupy the apical positions. The only exception is complex 5 (CoL4Cl ...
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