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Die lokale magnetische Anisotropie eines Low‐Spin‐Eisen(III)‐Komplexes wurde untersucht. In ihrer Zuschrift auf S. 4031 ff. zeigen B. Gillon, B. Le Guennic, R. Lescouëzec et al. das Leistungsvermögen von polarisierter Neutronenbeugung, mit der ein Bild der lokalen magnetischen Anisotropie‐ und Suszeptibilitätstensoren in Molekülen erstellt werden kann. Ein Weg wird gezeigt, um Beziehungen zwischen...
We have determined by polarized neutron diffraction (PND) the low‐temperature molecular magnetic susceptibility tensor of the anisotropic low‐spin complex PPh4[FeIII(Tp)(CN)3]⋅H2O. We found the existence of a pronounced molecular easy magnetization axis, almost parallel to the C3 pseudo‐axis of the molecule, which also corresponds to a trigonal elongation direction of the octahedral coordination sphere...
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