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New bidimensional cyanido-bridged heterometallic coordination polymers, [{Co(L 1 )} 3 {Fe(CN) 6 } 2 ]·6CH 3 OH·6H 2 O (1) and [{Fe(L 2 )} 3 {Co(CN) 6 } 2 ]·2CH 3 OH·13H 2 O (2), have been assembled following a building-block approach (L 1 and L 2 are macrocyclic ligands obtained by the template...
In order to assemble polynuclear iron(III) complexes, the coordination chemistry of the 2-hydroxyethyl-3,5-dimethylpyrazole (hedmp-H) ligand has been investigated. Reaction of hedmp-H with trinuclear iron carboxylate precursor [Fe 3 O(PhCOO) 6 (H 2 O) 3 ]Cl in acetonitrile yielded the hexanuclear Fe(III) complex [Fe 6 O 2 (OH) 2 (PhCOO) 10...
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