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Despite growing progress in the construction of chiral organosilicon compounds, the catalytic asymmetric synthesis of silicon‐stereogenic silanols is less explored and remains a considerable challenge. Herein, we report the first enantioselective construction of silicon‐stereogenic silanols by the catalytic asymmetric hydrolytic oxidation of dihydrosilanes. This practical procedure features ambient...
Despite growing progress in the construction of chiral organosilicon compounds, the catalytic asymmetric synthesis of silicon‐stereogenic silanols is less explored and remains a considerable challenge. Herein, we report the first enantioselective construction of silicon‐stereogenic silanols by the catalytic asymmetric hydrolytic oxidation of dihydrosilanes. This practical procedure features ambient...