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An isothermal titration calorimeter of the perfusion type (MicroCal model VP-ITC) is calibrated using the heat of dilution of NaCl in water. The relative apparent molar enthalpy function (L ϕ ) for NaCl(aq) varies strongly and nonlinearly with concentration in the low-concentration region (<0.2M) that is sampled easily and extensively in a single program of injections of NaCl solution into...
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